what do you mean with "path of the smtp profiles" ?
what information do you need in detail?
probably you will be able to find your the files under /var/chroot-smtp/etc but if you havent found them on your own so far (just by using the linux command "find") then I would recommend better not to play around on the command line as long as you are not amiliar with it. You will void your warranty if you accidentially break sometinhg on the command line.